Semi-Markov processes in open quantum systems. III. Large deviations of first-passage-time statistics

In a specific class of open quantum systems with finite and fixed numbers of collapsed quantum states, the semi-Markov process method is used to calculate the large deviations of the first passage time statistics. The core formula is an equation of poles, which is also applied in determining the scaled generating functions (SCGFs) of the counting statistics. For simple counting variables, the SCGFs of the first passage time statistics are derived by finding the largest modulus of the roots of this equation with respect to the z-transform parameter and then calculating its logarithm. The procedure is analogous to that of solving for the SCGFs of the counting statistics. However, for current-like variables, the method generally fails unless the equation of pole is simplified to a quadratic form. The fundamental reason for this lies in the nonuniqueness between the roots and the region of convergence for the joint transform. We illustrate these results via a resonantly driven two-level quantum system, where for several counting variables the solutions to the SCGFs of the first passage time are analytically obtained. Furthermore, we apply these functions to investigate quantum violations of the classical kinetic and thermodynamic uncertainty relations.