‘Kick-in the head’: high-performance and air-stable mononuclear Dy<sup>III</sup> single-molecule magnets with <i>pseudo-D</i><sub>6h</sub> symmetry from a [1 + 1] Schiff-base macrocycle approach
Using the [1 + 1] condensation approach for the preparation of new macrocyclic scaffolds with the phenanthroline-based ‘head’ unit afforded two Dy III monomers with pseudo-D 6h symmetry and large energy barriers for the magnetization reversal.
Authors
- Theocharis C. Stamatatos (ORCID: https://orcid.org/0000-0002-9798-9331)
- Richard A. Layfield (ORCID: https://orcid.org/0000-0002-6020-0309)
- Alexandros S. Armenis (ORCID: https://orcid.org/0000-0002-2955-415X)
- Dimitris I. Alexandropoulos (ORCID: https://orcid.org/0000-0002-8759-9495)
- S. R. Giblin (ORCID: https://orcid.org/0000-0003-1876-8619)
- Arpan Mondal (ORCID: https://orcid.org/0000-0001-9192-7255)
- Jinkui Tang (ORCID: https://orcid.org/0000-0002-8600-7718)
Institutions
- University of Sussex (GB)
- University of Patras (GR)
- Chinese Academy of Sciences (CN)
- Changchun Institute of Applied Chemistry (CN)
- Cardiff University (GB)
Publication Details
- Journal
- Inorganic Chemistry Frontiers
- Published
- 2024-12-23
- DOI
- https://doi.org/10.1039/d4qi02756f
- Citations
- 14
- Primary Topic
- Magnetism in coordination complexes
- Type
- article
- Field-Weighted Citation Impact
- 1.65
Funders
- National Natural Science Foundation of China
- Engineering and Physical Sciences Research Council