Cover Feature: Thermochemistry of Solid‐State Formation, Structure, Optical, and Luminescent Properties of Complex Oxides Eu<sub>2</sub>MeO<sub>6</sub> (Me–Mo, W), Eu<sub>2</sub>W<sub>2</sub>O<sub>9</sub>: A Combined Experimental and DFT Study (Chem.
Complex oxides Eu2MeO6 (Me=Mo, W) and Eu2W2O9 were obtained in a solid-phase reaction between binary oxides. The thermodynamic and kinetic mechanisms of the reaction processes were established by using a variety of physicochemical methods. Calculations of absorption spectra are shown to be superior to band structure analysis in the determination of optical band gaps. In this work, the experimental data are in good agreement with the theoretical models. More information can be found in the Research Article by Yu. G. Denisenko and co-workers (DOI: 10.1002/chem.202402084).
Authors
- Nikita O. Azarapin (ORCID: https://orcid.org/0000-0003-1510-9749)
- Nikolay A. Khritokhin (ORCID: https://orcid.org/0000-0002-8887-6263)
- Мaxim S. Моlokeev (ORCID: https://orcid.org/0000-0002-8297-0945)
- Aleksandr S. Oreshonkov (ORCID: https://orcid.org/0000-0003-3046-7018)
- Maksim A. Zhernakov (ORCID: https://orcid.org/0000-0002-0339-5365)
- Alexander E. Sedykh (ORCID: https://orcid.org/0000-0003-2650-5173)
- Klaus Müller‐Buschbaum (ORCID: https://orcid.org/0000-0002-2857-8379)
- Yulia V. Seredina
- Aleksandr S. Aleksandrovsky (ORCID: https://orcid.org/0000-0003-1821-6718)
- Yuriy G. Denisenko (ORCID: https://orcid.org/0000-0003-3453-5188)
- Natalia A. Shelpakova
- Polina О. Glukhova
Institutions
- Justus-Liebig-Universität Gießen (DE)
- Kazan Federal University (RU)
- University of Tyumen (RU)
- Industrial University of Tyumen (RU)
- Institute of Physics (RU)
- Siberian Federal University (RU)
Publication Details
- Journal
- Chemistry - A European Journal
- Published
- 2024-09-19
- DOI
- https://doi.org/10.1002/chem.202485302
- Primary Topic
- Luminescence Properties of Advanced Materials
- Type
- article
- Field-Weighted Citation Impact
- 0.00