Macrocycle- and metal-centered reduction of cobalt trithiadodecaazahexaphyrin (Hhp). Metal-to-ligand charge transfer in {(CoI2Co <sup>II</sup> O)(Hhp˙ <sup>4−</sup> )} <sup>2−</sup>
Crystals of {Cryptand(K + )} 2 {(CoI2Co II O) 2+ (Hhp˙ 4− )} 2− ·2C 6 H 4 Cl 2 (1) were obtained from H 3 Hhp and Co II (acac) 2 under reduction. Salt 1 demonstrates a metal-to-macrocycle charge transfer and low-energy d–π optical transition.
Authors
- Salavat S. Khasanov (ORCID: https://orcid.org/0000-0003-1255-4273)
- Dmitry I. Nazarov (ORCID: https://orcid.org/0000-0002-2155-4788)
- Akihiro Otsuka (ORCID: https://orcid.org/0000-0002-3141-0702)
- Alexander F. Shestakov (ORCID: https://orcid.org/0000-0001-8819-8960)
- Evgenii N. Ivanov (ORCID: https://orcid.org/0000-0003-1174-6433)
- Maxim A. Faraonov (ORCID: https://orcid.org/0000-0003-0805-601X)
- Hiroshi Kitagawa (ORCID: https://orcid.org/0000-0001-6955-3015)
- Dmitri V. Konarev
- Hideki Yamochi (ORCID: https://orcid.org/0000-0002-0127-6530)
- Mikhail K. Islyaikin (ORCID: https://orcid.org/0000-0003-0070-0704)
- Alexey V. Kuźmin (ORCID: https://orcid.org/0000-0001-8218-4058)
Institutions
- Kyoto University (JP)
- Ivanovo State University of Chemistry and Technology (RU)
- Osipyan Institute of Solid State Physics RAS (RU)
- Institute of Problems of Chemical Physics (RU)
Publication Details
- Journal
- New Journal of Chemistry
- Published
- 2024-12-20
- DOI
- https://doi.org/10.1039/d4nj04896b
- Primary Topic
- Porphyrin and Phthalocyanine Chemistry
- Type
- article
- Field-Weighted Citation Impact
- 0.00