A multi-responsive 3D deformable soft actuator with tunable structural color enabled by a graphene/cholesteric liquid crystal elastomer composite

Intelligent soft robots that integrate both structural color and controllable actuation ability have attracted substantial attention for constructing biomimetic systems, biomedical devices, and soft robotics. However, simultaneously endowing single-layer cholesteric liquid crystal elastomer (CLCE) soft actuators with reversible 3D deformability and vivid structural color changes is still challenging. Herein, a multi-responsive (force, heat and light) single-layer 3D deformable soft actuator with vivid structural color-changing ability is realized through the reduced graphene oxide (RGO) deposition-induced Janus structure of the CLCE using a precisely-controlled evaporation method. This single-layer structural color soft actuator can directly transform from a flat shape to a 3D shape through the photothermal effect. The introduction of RGO not only improves the mechanical properties and color saturation of the CLCE, but also endows it with near-infrared (NIR) light responsiveness <i>via</i> the photothermal effect. Moreover, due to the structural gradient resulting from the spontaneous deposition of RGO during the deswelling process, CLCEs show a stacked structure of the helical CLC layer and RGO-dispersed amorphous layer, which are capable of undergoing multiple reversible 3D deformations. The reversible deformations of biomimetic devices such as petal-like films imitating blooming flowers, thin strips imitating plant tendrils, and a cobweb-inspired catching net are achieved to demonstrate applications of this single-layer RGO/CLCE composite film. This work provides a simple strategy for the construction of single-layer 3D deformable soft actuators.