Diamine Crosslinked Addition-Type Diblock Poly(Norbornene)s-Based Anion Exchange Membranes with High Conductivity and Stability for Fuel Cell Applications

Anion exchange membranes (AEMs) as a kind of important functional material are widely used in fuel cells. However, synthetic AEMs generally suffer from low conductivity, poor alkaline stability, and poor dimensional stability. Constructing efficient ion transport channels is widely regarded as one of the most effective strategies for developing AEMs with high conductivity and low swelling ratio. Herein we demonstrate a versatile strategy to prepare the AEMs with both high conductivity and excellent alkali stability via all-carbon hydrogen block copolymer backbone hydrophilic crosslinking and introducing flexible alkoxy spacer chains. Additionally, we investigated the impact of the crosslinking degree on the AEMs' performances. It was found that the dosage of the hydrophilic crosslinker has a significant impact on the construction of efficient ion transport channels in the AEMs. Amazingly, the CL30-aPNB-TMHDA-TMA exhibited the highest hydroxide conductivity (138.84 mS cm^-1), reasonable water uptake (54.96%), and a low swelling ratio (14.07%) at 80 °C. Meanwhile, the membrane showed an excellent alkaline stability in a 1 M NaOH solution at 80 °C for 1008 h (ion exchange capacity (IEC) and OH^- conductivity remained at 91.9% and 89.12%, respectively). The single cells assembled with CL30-aPNB-TMHDA-TMA exhibited a peak power density of 266.2 mW cm^-2 under a current density of 608 mA cm^-2 at 80 °C. The novel developed composite strategy of flexible alkoxy side chains with hydrophilic crosslinking modification is potentially promised to be an effective approach to develop the high-performance AEMs.