A nickel metalloradical bearing a phenalenyl-based tridentate ligand
Abstract A nickel(I) complex 1 bearing a phenalenyl-based tridentate ligand was synthesized. The electronic and spin structures of 1 were elucidated through electronic absorption spectra, electron spin resonance, and X-ray absorption fine structure measurements. Additionally, the metalloradical reactivity of 1 toward diphenyl disulfide and alkyl halides was also demonstrated.
Authors
- Mamoru Tobisu (ORCID: https://orcid.org/0000-0002-8415-2225)
- Seiji Yamazoe (ORCID: https://orcid.org/0000-0002-8382-8078)
- Hikaru Noguchi (ORCID: https://orcid.org/0009-0000-9797-2110)
- Soichi Kikkawa (ORCID: https://orcid.org/0000-0002-8193-6374)
- Takuya Kodama (ORCID: https://orcid.org/0000-0001-8275-2393)
Institutions
- Tokyo Metropolitan University (JP)
- The University of Osaka (JP)
Publication Details
- Journal
- Chemistry Letters
- Published
- 2024-11-29
- DOI
- https://doi.org/10.1093/chemle/upae236
- Citations
- 2
- Primary Topic
- Organometallic Complex Synthesis and Catalysis
- Type
- article
- Field-Weighted Citation Impact
- 0.50