Reactivity of hypervalent iodine(III) reagents bearing a benzylamine with sulfenate salts
The reactivity of our recently disclosed hypervalent iodine reagents (HIRs) bearing a benzylamine with in situ-generated sulfenate salts was investigated. Under the studied conditions sulfonamides have been obtained in up to 52% yield. This reaction has been extended to a variety of HIRs and sulfenate salts to explore the different reactivity of these new reagents. A plausible mechanism is proposed, suggesting a possible radical pathway.
Authors
- José Cunha (ORCID: https://orcid.org/0000-0002-6957-0330)
- M. Manuel B. Marques
- Clara S. B. Gomes (ORCID: https://orcid.org/0000-0003-3672-0045)
- Catarina Caldeira
- Beatriz Dedeiras (ORCID: https://orcid.org/0009-0006-2527-101X)
Institutions
- Universidade Nova de Lisboa (PT)
Publication Details
- Journal
- Beilstein Journal of Organic Chemistry
- Published
- 2024-12-19
- DOI
- https://doi.org/10.3762/bjoc.20.272
- Citations
- 2
- Primary Topic
- Oxidative Organic Chemistry Reactions
- Type
- article
- Field-Weighted Citation Impact
- 0.50
Funders
- Ministério da Ciência, Tecnologia e Ensino Superior
- Laboratório Associado para a Química Verde
- Fundação para a Ciência e a Tecnologia
- European Regional Development Fund