Synthesis of Functionally Substituted 4H-Thiopyrans by Reaction of Carbon Disulfide with Malononitrile Trimer

Abstract Tripotassium 2-(1-cyano-2,2-disulfidoethenyl)-1,1,3,3-tetracyanopropenide was synthesized for the first time by the reaction of carbon disulfide and malononitrile trimer. Its further transformations afforded 2-amino-4-(dicyanomethylidene)-4 H -thiopyran-3,5-dicarbonitrile derivatives.

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Publication Details

Journal
Russian Journal of Organic Chemistry
Published
2024-10-01
DOI
https://doi.org/10.1134/s1070428024100038
Primary Topic
Synthesis of heterocyclic compounds
Type
article
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article

Synthesis of Functionally Substituted 4H-Thiopyrans by Reaction of Carbon Disulfide with Malononitrile Trimer

К. В. Липин, И. Н. Бардасов, S. A. Blinov
Russian Journal of Organic Chemistry
Synthesis of heterocyclic compounds
article

Synthesis of Functionally Substituted 4H-Thiopyrans by Reaction of Carbon Disulfide with Malononitrile Trimer

К. В. Липин, И. Н. Бардасов, S. A. Blinov
article en

Abstract

Abstract Tripotassium 2-(1-cyano-2,2-disulfidoethenyl)-1,1,3,3-tetracyanopropenide was synthesized for the first time by the reaction of carbon disulfide and malononitrile trimer. Its further transformations afforded 2-amino-4-(dicyanomethylidene)-4 H -thiopyran-3,5-dicarbonitrile derivatives.

Russian Journal of Organic ChemistryVol. 60(10)
Chuvash State University (RU)
Clean water and sanitation
Openalex Percentile: Top 83%
Synthesis of heterocyclic compounds
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