Reduction of iron porphyrin nitrate to the iron nitrosyl by H<sub>2</sub>S/thiol. studies in sublimed layers
Hemes play key roles in enzymatic production of the mammalian gasotransmitter NO by nitric oxide synthase as well as in conversion from inorganic nitrite. In the present study, we report a hitherto unknown pathway of nitrosyl formation <i>via</i> thiol reduction of a iron porphyrin nitrate complex in the solid state.
Authors
- Alexei V. Iretskii (ORCID: https://orcid.org/0000-0002-0226-5788)
- Garik G. Martirosyan (ORCID: https://orcid.org/0000-0002-0150-6172)
- Astghik A. Hovhannisyan
- Peter C. Ford (ORCID: https://orcid.org/0000-0002-5509-9912)
Institutions
- Lake Superior State University (US)
- University of California, Santa Barbara (US)
- Institute of Fine Organic Chemistry of Scientific - Technological Center of Organic and Pharmaceutical Chemistry (AM)
Publication Details
- Journal
- Chemical Communications
- Published
- 2024-12-18
- DOI
- https://doi.org/10.1039/d4cc06229a
- Citations
- 3
- Primary Topic
- Photoreceptor and optogenetics research
- Type
- article
- Field-Weighted Citation Impact
- 0.80