From single atoms to nanoparticles: size effect on Pd/C-catalyzed hydrogenation of 2,5-furandicarboxylic acid
In this study, five catalysts with Pd particle sizes ranging from single atoms to nanoclusters and nanoparticles were synthesized by controlling the Pd loading amount and preparation methods, and applied in the hydrogenation of FDCA to THFDCA. Furthermore, kinetic models were established. Notably, the nanocluster catalyst demonstrated relatively high hydrogenation activity.
Authors
- Jiali Zheng (ORCID: https://orcid.org/0009-0003-1826-5285)
- Yanji Wang (ORCID: https://orcid.org/0000-0003-2862-0992)
- Xinqiang Zhao (ORCID: https://orcid.org/0000-0002-9399-7289)
- Dongsheng Zhang (ORCID: https://orcid.org/0000-0002-7996-910X)
- Zhihui Li (ORCID: https://orcid.org/0009-0001-2809-8850)
- Qian Zhao (ORCID: https://orcid.org/0000-0001-8804-1541)
Institutions
- Hebei University of Technology (CN)
Publication Details
- Journal
- Chemical Communications
- Published
- 2024-12-18
- DOI
- https://doi.org/10.1039/d4cc05105j
- Primary Topic
- Catalysis for Biomass Conversion
- Type
- article
- Field-Weighted Citation Impact
- 0.00
Funders
- National Natural Science Foundation of China