Mechanochemical generation of nitrogen-centred radicals for the formation of tertiary amines in polymers
Carbamoylketoximes of N -pentenyl-substituted secondary amines give access to cyclic tertiary amine bases by a subsequent 5- exo-trig cyclization after homolytic bond scission of the mechanophore induced through polymer mechanochemistry.
Authors
- Robert Göstl (ORCID: https://orcid.org/0000-0002-7483-6236)
- Simay Aydonat (ORCID: https://orcid.org/0000-0002-0210-1601)
- Davide Campagna (ORCID: https://orcid.org/0000-0003-2815-9630)
- Sonja Storch (ORCID: https://orcid.org/0009-0008-4253-8606)
Institutions
- University of Wuppertal (DE)
- DWI – Leibniz Institute for Interactive Materials (DE)
- RWTH Aachen University (DE)
Publication Details
- Journal
- RSC Mechanochemistry
- Published
- 2024-12-18
- DOI
- https://doi.org/10.1039/d4mr00099d
- Citations
- 3
- Primary Topic
- Force Microscopy Techniques and Applications
- Type
- article
- Field-Weighted Citation Impact
- 1.01
Funders
- Deutsche Forschungsgemeinschaft
- Bundesministerium für Bildung und Forschung