Synthesis and Structure of Porphyrin(2.1.2.1) Bows
A new series of porphyrin(2.1.2.1) arches have been successfully synthesized by using porphyrin(2.1.2.1) as natural "arch limbs" for the construction of the arches. X-ray single-crystal diffraction revealed that the porphyrin(2.1.2.1) derivatives have a beautiful bow-shaped structure. The strong, rigid structure of the porphyrin(2.1.2.1) bow prevents hydrogenation with the Lindlar catalyst. The heterogeneous electrocatalytic HER activity of the porphyrin(2.1.2.1) bow indicated that the "bowstring" butadiyne-bridge reduced the HER capacity.
Authors
- Daiki Kuzuhara (ORCID: https://orcid.org/0000-0001-7948-8501)
- Fengxian Qiu (ORCID: https://orcid.org/0000-0001-7475-7565)
- Hongliang Huang (ORCID: https://orcid.org/0000-0001-9690-9259)
- Zijian Gao (ORCID: https://orcid.org/0000-0003-3864-738X)
- Songlin Xue (ORCID: https://orcid.org/0000-0002-6197-1885)
- Yemei Wang
- Jinrong Wu
- Daichi Yoshikawa
Institutions
- Jiangsu University (CN)
- Iwate University (JP)
- Tiangong University (CN)
- Jiangsu University of Science and Technology (CN)
Publication Details
- Journal
- Inorganic Chemistry
- Published
- 2024-12-18
- DOI
- https://doi.org/10.1021/acs.inorgchem.4c03813
- Citations
- 2
- Primary Topic
- Porphyrin and Phthalocyanine Chemistry
- Type
- article
- Field-Weighted Citation Impact
- 0.23
Funders
- National Natural Science Foundation of China
- Japan Society for the Promotion of Science
- Institute for Chemical Research, Kyoto University