The Boltzmann Equation and Its Place in the Edifice of Statistical Mechanics

It is customary to classify approaches in statistical mechanics (SM) as belonging either to Boltzmanninan SM (BSM) or Gibbsian SM (GSM). It is, however, unclear how the Boltzmann equation (BE) fits into either of these approaches. To discuss the relation between BE and BSM, we first present a version of BSM that differs from standard presentation in that it uses local field variables to individuate macro-states, and we then show that BE is a special case of BSM <i>thus understood</i>. To discuss the relation between BE and GSM, we focus on the BBGKY hierarchy and note the version of the BE that follows from the hierarchy is "Gibbsian" only in the minimal sense that it operates with an invariant measure on the state space of the full system.

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Publication Details

Journal
Entropy
Published
2024-12-18
DOI
https://doi.org/10.3390/e26121106
Citations
3
Primary Topic
Theoretical and Computational Physics
Type
article
Field-Weighted Citation Impact
0.93

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article

The Boltzmann Equation and Its Place in the Edifice of Statistical Mechanics

Roman Frigg, Charlotte Werndl
3 citations
Entropy
Theoretical and Computational Physics
0.93
article

The Boltzmann Equation and Its Place in the Edifice of Statistical Mechanics

Roman Frigg, Charlotte Werndl
article en
3 citations

Abstract

It is customary to classify approaches in statistical mechanics (SM) as belonging either to Boltzmanninan SM (BSM) or Gibbsian SM (GSM). It is, however, unclear how the Boltzmann equation (BE) fits into either of these approaches. To discuss the relation between BE and BSM, we first present a version of BSM that differs from standard presentation in that it uses local field variables to individuate macro-states, and we then show that BE is a special case of BSM <i>thus understood</i>. To discuss the relation between BE and GSM, we focus on the BBGKY hierarchy and note the version of the BE that follows from the hierarchy is "Gibbsian" only in the minimal sense that it operates with an invariant measure on the state space of the full system.

EntropyVol. 26(12)
University of Salzburg (AT), London School of Economics and Political Science (GB)
Austrian Science Fund
Sustainable cities and communities
Openalex Percentile: Top 25%
Theoretical and Computational Physics
0.93
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The Boltzmann Equation and Its Place in the Edifice of Statistical Mechanics — Roman Frigg, Charlotte Werndl · Entropy (2024) | TGRS Research Map | TGRS