Thermal Rectification in Telescopic Nanowires: Impact of Thermal Boundary Resistance

A thermal diode, which, by analogy to its electrical counterpart, rectifies heat current, is the building block for thermal circuits. To realize a thermal diode, we demonstrate thermal rectification in a GaAs telescopic nanowire system using the thermal bridge method. We measured a preferred direction of heat flux, achieving rectification values ranging from 2 to 8% as a function of applied thermal bias. We demonstrate that the thermal boundary resistance between the thin part with the wurtzite crystal phase and the thick part with the zinc-blende crystal phase of the telescopic nanowire plays a crucial role in determining the amount and direction of heat flux rectification. This effect is confirmed by numerical solutions of the one-dimensional heat equation based on ab initio data. Additionally, we accounted for the effect of the thermal contact resistance. This work is the first experimental indication of rectification using a telescopic nanowire where we reveal the importance and role of the thermal boundary resistance in determining thermal rectification.

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Publication Details

Journal
ACS Applied Materials & Interfaces
Published
2024-12-18
DOI
https://doi.org/10.1021/acsami.4c14920
Citations
3
Primary Topic
Thermal properties of materials
Type
article
Field-Weighted Citation Impact
0.35

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Thermal Rectification in Telescopic Nanowires: Impact of Thermal Boundary Resistance

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article

Thermal Rectification in Telescopic Nanowires: Impact of Thermal Boundary Resistance

Riccardo Rurali, Saeko Tachikawa, Anna Fontcuberta i Morral, Milo Yaro Swinkels, Miquel López-Suárez, Yashpreet Kaur, Alicia Ruiz‐Caridad, Wonjong Kim, Ilaria Zardo, Matteo Camponovo
article en
3 citations

Abstract

A thermal diode, which, by analogy to its electrical counterpart, rectifies heat current, is the building block for thermal circuits. To realize a thermal diode, we demonstrate thermal rectification in a GaAs telescopic nanowire system using the thermal bridge method. We measured a preferred direction of heat flux, achieving rectification values ranging from 2 to 8% as a function of applied thermal bias. We demonstrate that the thermal boundary resistance between the thin part with the wurtzite crystal phase and the thick part with the zinc-blende crystal phase of the telescopic nanowire plays a crucial role in determining the amount and direction of heat flux rectification. This effect is confirmed by numerical solutions of the one-dimensional heat equation based on ab initio data. Additionally, we accounted for the effect of the thermal contact resistance. This work is the first experimental indication of rectification using a telescopic nanowire where we reveal the importance and role of the thermal boundary resistance in determining thermal rectification.

ACS Applied Materials & InterfacesVol. 17(1)
University of Basel (CH), Institut de Ciència de Materials de Barcelona (ES), Swiss Nanoscience Institute, École Polytechnique Fédérale de Lausanne (CH)
Ministerio de Ciencia, Innovación y Universidades, Fundación Carmen y Severo Ochoa, European Commission, Generalitat de Catalunya, Agencia Estatal de Investigación, H2020 European Research Council
Openalex Percentile: Top 42%
Thermal properties of materials
0.35
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