Multiphase Janus Azobenzene Inverse Opal Membrane toward On-Demand Photocontrolled Motion

Azobenzene actuators have generated extensive research investment in the field of soft robots, artificial muscles, etc., based on the typical photoresponsive <i>trans</i>-<i>cis</i> isomerization. However, it remains challenging to achieve multiphase actuation at the gas-liquid interface and liquid phase. To solve these problems, this paper demonstrated a simple fabrication method of a Janus azobenzene inverse opal membrane with one side having a polydomain azobenzene inverse opal structure and the other side having a monodomain bulk azobenzene polymer. The introduction of an inverse opal structure increases the interaction area between the liquid and polymer network. The proposed design can freely swim in any direction at the air-liquid interface based on the Marangoni effect or move forward in the liquid phase based on bubble propulsion under UV irradiation. This work is of great significance for the design and fabrication of multiphase photo actuators.

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Publication Details

Journal
ACS Applied Materials & Interfaces
Published
2024-12-18
DOI
https://doi.org/10.1021/acsami.4c18563
Citations
4
Primary Topic
Advanced Materials and Mechanics
Type
article
Field-Weighted Citation Impact
0.85

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article

Multiphase Janus Azobenzene Inverse Opal Membrane toward On-Demand Photocontrolled Motion

Pan Jia, Zhong Yu, Jinfen Niu, Jingxia Wang et al.
4 citations
ACS Applied Materials & Interfaces
Advanced Materials and Mechanics
0.85
article

Multiphase Janus Azobenzene Inverse Opal Membrane toward On-Demand Photocontrolled Motion

Pan Jia, Zhong Yu, Jinfen Niu, Jingxia Wang, Songtao Shao, Ningning Zhao, Xiaojiao Yu, Junchao Liu
article en
4 citations

Abstract

Azobenzene actuators have generated extensive research investment in the field of soft robots, artificial muscles, etc., based on the typical photoresponsive <i>trans</i>-<i>cis</i> isomerization. However, it remains challenging to achieve multiphase actuation at the gas-liquid interface and liquid phase. To solve these problems, this paper demonstrated a simple fabrication method of a Janus azobenzene inverse opal membrane with one side having a polydomain azobenzene inverse opal structure and the other side having a monodomain bulk azobenzene polymer. The introduction of an inverse opal structure increases the interaction area between the liquid and polymer network. The proposed design can freely swim in any direction at the air-liquid interface based on the Marangoni effect or move forward in the liquid phase based on bubble propulsion under UV irradiation. This work is of great significance for the design and fabrication of multiphase photo actuators.

ACS Applied Materials & InterfacesVol. 17(1)
Chinese Academy of Sciences (CN), Xi'an University of Technology (CN), Technical Institute of Physics and Chemistry (CN), Shaanxi University of Science and Technology (CN), Hebei Normal University (CN)
National Natural Science Foundation of China, Chinese Academy of Sciences, Xi'an University of Technology, Scientific Research Plan Projects of Shaanxi Education Department, Natural Science Basic Research Program of Shaanxi Province
Affordable and clean energy
Openalex Percentile: Top 29%
Advanced Materials and Mechanics
0.85
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