Wafer level Demonstration and Characterization of c-Axis Oriented Sc<sub>0.3</sub>Al<sub>0.7</sub>N Bilayer Stacks

In this study, we investigated c-axis oriented single-layer and bilayer stack of Sc<inf xmlns:mml="http://www.w3.org/1998/Math/MathML" xmlns:xlink="http://www.w3.org/1999/xlink">0.3</inf>Al<inf xmlns:mml="http://www.w3.org/1998/Math/MathML" xmlns:xlink="http://www.w3.org/1999/xlink">0.7</inf>N films, focusing on the film microstructures and piezoelectric properties across various piezoelectric film layer thicknesses. Mo thickness of 2 kÅ was used as the bottom, middle and top electrode layers. Various film stacks with Sc<inf xmlns:mml="http://www.w3.org/1998/Math/MathML" xmlns:xlink="http://www.w3.org/1999/xlink">0.3</inf>Al<inf xmlns:mml="http://www.w3.org/1998/Math/MathML" xmlns:xlink="http://www.w3.org/1999/xlink">0.7</inf>N layer thickness of 1 kÅ, 3 kÅ, 5 kÅ, 7.5 kÅ and 10 kÅ were deposited and characterized. With Sc<inf xmlns:mml="http://www.w3.org/1998/Math/MathML" xmlns:xlink="http://www.w3.org/1999/xlink">0.3</inf>Al<inf xmlns:mml="http://www.w3.org/1998/Math/MathML" xmlns:xlink="http://www.w3.org/1999/xlink">0.7</inf>N thickness varying from 1 kÅ to 10 kÅ, the film texture, (measured from XRD rocking curve FWHM), improved from 2° to 1.3°, the effective piezoelectric coefficients, d<inf xmlns:mml="http://www.w3.org/1998/Math/MathML" xmlns:xlink="http://www.w3.org/1999/xlink">33,f</inf> increased from 9.5 pm/V to 11.3 pm/V, e<inf xmlns:mml="http://www.w3.org/1998/Math/MathML" xmlns:xlink="http://www.w3.org/1999/xlink">31,f</inf> changed from -1.76 C/m<sup xmlns:mml="http://www.w3.org/1998/Math/MathML" xmlns:xlink="http://www.w3.org/1999/xlink">2</sup> to -2.09 C/m<sup xmlns:mml="http://www.w3.org/1998/Math/MathML" xmlns:xlink="http://www.w3.org/1999/xlink">2</sup>. Comparable or even better ScAlN (0002) orientation can be achieved for the bilayer film stacks. The effective piezoelectric coefficient difference between the first and second Sc<inf xmlns:mml="http://www.w3.org/1998/Math/MathML" xmlns:xlink="http://www.w3.org/1999/xlink">0.3</inf>Al<inf xmlns:mml="http://www.w3.org/1998/Math/MathML" xmlns:xlink="http://www.w3.org/1999/xlink">0.7</inf>N layers is less than 3%.

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Published
2024-09-22
DOI
https://doi.org/10.1109/uffc-js60046.2024.10793771
Citations
1
Primary Topic
Semiconductor materials and devices
Type
article
Field-Weighted Citation Impact
0.21

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article

Wafer level Demonstration and Characterization of c-Axis Oriented Sc0.3Al0.7N Bilayer Stacks

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1 citations
Semiconductor materials and devices
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article

Wafer level Demonstration and Characterization of c-Axis Oriented Sc0.3Al0.7N Bilayer Stacks

Dao Hao Sim, Alberto Leotti, A. K. Das, Yao Zhu, Tak‐Sing Wong, Naadaa Zakiyyan, Binni Varghese, Peng Fei Liu, Peter Hyun Kee Chang, Qing Xin Zhang, Daniel Ssu-Han Chen, Goutham Koppisetti, Minghua Li, Hong Yan, Huamao Lin, Yee Lung Lee, Yat Fung Tsang
article en
1 citations

Abstract

In this study, we investigated c-axis oriented single-layer and bilayer stack of Sc<inf xmlns:mml="http://www.w3.org/1998/Math/MathML" xmlns:xlink="http://www.w3.org/1999/xlink">0.3</inf>Al<inf xmlns:mml="http://www.w3.org/1998/Math/MathML" xmlns:xlink="http://www.w3.org/1999/xlink">0.7</inf>N films, focusing on the film microstructures and piezoelectric properties across various piezoelectric film layer thicknesses. Mo thickness of 2 kÅ was used as the bottom, middle and top electrode layers. Various film stacks with Sc<inf xmlns:mml="http://www.w3.org/1998/Math/MathML" xmlns:xlink="http://www.w3.org/1999/xlink">0.3</inf>Al<inf xmlns:mml="http://www.w3.org/1998/Math/MathML" xmlns:xlink="http://www.w3.org/1999/xlink">0.7</inf>N layer thickness of 1 kÅ, 3 kÅ, 5 kÅ, 7.5 kÅ and 10 kÅ were deposited and characterized. With Sc<inf xmlns:mml="http://www.w3.org/1998/Math/MathML" xmlns:xlink="http://www.w3.org/1999/xlink">0.3</inf>Al<inf xmlns:mml="http://www.w3.org/1998/Math/MathML" xmlns:xlink="http://www.w3.org/1999/xlink">0.7</inf>N thickness varying from 1 kÅ to 10 kÅ, the film texture, (measured from XRD rocking curve FWHM), improved from 2° to 1.3°, the effective piezoelectric coefficients, d<inf xmlns:mml="http://www.w3.org/1998/Math/MathML" xmlns:xlink="http://www.w3.org/1999/xlink">33,f</inf> increased from 9.5 pm/V to 11.3 pm/V, e<inf xmlns:mml="http://www.w3.org/1998/Math/MathML" xmlns:xlink="http://www.w3.org/1999/xlink">31,f</inf> changed from -1.76 C/m<sup xmlns:mml="http://www.w3.org/1998/Math/MathML" xmlns:xlink="http://www.w3.org/1999/xlink">2</sup> to -2.09 C/m<sup xmlns:mml="http://www.w3.org/1998/Math/MathML" xmlns:xlink="http://www.w3.org/1999/xlink">2</sup>. Comparable or even better ScAlN (0002) orientation can be achieved for the bilayer film stacks. The effective piezoelectric coefficient difference between the first and second Sc<inf xmlns:mml="http://www.w3.org/1998/Math/MathML" xmlns:xlink="http://www.w3.org/1999/xlink">0.3</inf>Al<inf xmlns:mml="http://www.w3.org/1998/Math/MathML" xmlns:xlink="http://www.w3.org/1999/xlink">0.7</inf>N layers is less than 3%.

Agency for Science, Technology and Research (SG), Institute of Microelectronics (SG), STMicroelectronics (Singapore) (SG)
Science and Engineering Research Council
Openalex Percentile: Top 45%
Semiconductor materials and devices
0.21
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