Reaction mechanism with indano[60]fullerene bromide for evaporable fullerene derivatives
Indano[60]fullerene bromide was isolated as a key intermediate in the synthesis of indano[60]fullerene ketone, an evaporable fullerene derivative. Based on the identified reaction mechanism, aqueous hydrobromic acid was used to achieve reproducible and high-yielding reactions. A scalable one-pot reaction from aryl[60]fullerenyl dimers to indano[60]fullerene ketone was also demonstrated.
Authors
- Kazuhira Miwa
- Kin‐ichi Oyama (ORCID: https://orcid.org/0000-0003-3715-7987)
- Qing‐Jun Shui (ORCID: https://orcid.org/0000-0003-4227-2701)
- Hao‐Sheng Lin (ORCID: https://orcid.org/0000-0003-1947-4954)
- Yutaka Matsuo (ORCID: https://orcid.org/0000-0001-9084-9670)
- Hirofumi Amada
- Koki Yamanaka
- Yong‐Chang Zhai
Institutions
- Nagoya University (JP)
Publication Details
- Journal
- Chemical Communications
- Published
- 2024-12-18
- DOI
- https://doi.org/10.1039/d4cc05600k
- Primary Topic
- Fullerene Chemistry and Applications
- Type
- article
- Field-Weighted Citation Impact
- 0.00