Synthesis of Monosubstituted Derivatives of 4,5-Dichlorophthalonitrile in a DMF–Water System
A simple procedure was developed for the synthesis of undescribed 4-aryloxy-5-chlorophthalonitriles and 4-arylsulfanyl-5-chlorophthalonitriles by SNAr reaction of 4,5-dichlorophthalonitrile with phenols and thiophenols in a DMF–water binary solvent. The resulting ortho-dicarbonitriles are of interest as precursors for the synthesis of phthalocyanines. The product yields ranged from 30 to 59%.
Authors
- A. E. Rassolova (ORCID: https://orcid.org/0000-0002-0320-6376)
- V. V. Bukhalin
- V. V. Aleksandriiskii (ORCID: https://orcid.org/0000-0002-7986-6573)
- V. L. Baklagin (ORCID: https://orcid.org/0009-0003-5361-9085)
- И. Г. Абрамов (ORCID: https://orcid.org/0000-0002-8204-1660)
- В. Е. Майзлиш
Institutions
- Ivanovo State University (RU)
- Yaroslavl State Technical University (RU)
Publication Details
- Journal
- Russian Journal of General Chemistry
- Published
- 2024-11-01
- DOI
- https://doi.org/10.1134/s1070363224110069
- Citations
- 1
- Primary Topic
- Synthesis and Reactions of Organic Compounds
- Type
- article
- Field-Weighted Citation Impact
- 0.25