Optimizing <i>s–p</i> Orbital Overlap Between Sodium Polysulfides and Single‐Atom Indium Catalyst for Efficient Sulfur Redox Reaction

Abstract P‐ block metal carbon‐supported single‐atom catalysts (C‐SACs) have emerged as a promising candidate for high‐performance room‐temperature sodium‐sulfur (RT Na−S) batteries, due to their high atom utilization and unique electronic structure. However, the ambiguous electronic‐level understanding of Na‐dominant s‐p hybridization between sodium polysulfides (NaPSs) and p‐ block C‐SACs limits the precise control of coordination environment tuning and electro‐catalytic activity manipulation. Here, s‐p orbital overlap degree (OOD) between the s orbitals of Na in NaPSs and the p orbitals of p‐ block C‐SACs is proposed as a descriptor for sulfur reduction reaction (SRR) and sulfur oxidation reaction (SOR). Compared to NG and NG‐supported InN 4 (NG‐InN 4 ) SACs, the nitrogen‐doped graphene‐supported InN 5 (NG‐InN 5 ) SACs show the largest s‐p OOD, demonstrating the weakest shuttle effect and the lowest reaction energy barriers in both SRR and SOR. Accordingly, the designed catalysts allow the Na−S pouch batteries to retain a high capacity of 490.7 mAh g −1 at 2 A g −1 with a Coulombic efficiency of 96 % at a low electrolyte/sulfur (E/S) ratio of 4.5 μl mg −1 . This work offers an s‐p orbital overlap descriptor describing the interaction between NaPSs and p‐ orbital‐dominated catalysts for high‐performance RT Na−S batteries.