Crystal structure of <i>catena</i>-poly[bis(<i>N</i>,<i>O</i>-dimethylhydroxylammonium) [di-μ-bromido-dibromidostannate(II)]]

The title compound, {(C₂H₈NO)₂[SnBr₄]} _<i>n</i> , is a layered hybrid perovskite crystallizing in the monoclinic space group <i>C</i>2/<i>c</i>. The asymmetric unit consists of one H₃C-O-NH₂ ⁺-CH₃ cation (Me₂HA⁺), one Sn^II atom located on a twofold rotation axis, and two Br atoms. The Sn^II atom has a distorted octa-hedral coordination environment formed by the bromido ligands. The {SnBr₆} units corner-share their equatorial Br atoms, forming infinite mono-layers that extend parallel to the <i>ab</i> plane. These inorganic layers are sandwiched by the organic Me₂HA⁺ cations organized in double-layers; stacking of the layers is along the <i>c-</i>axis direction. Consecutive inorganic layers, separated by the organic cations, are shifted relative to each other along the <i>b</i>-axis direction. Specifically, the Sn^II atom in one inorganic layer is offset by 3.148 Å along the <i>b</i> axis relative to the Sn^II atom in an adjacent inorganic layer. The <i>N</i>,<i>O</i>-di-methyl-hydroxyl-ammonium cation forms two hydrogen bonds with the axial bromide anions of the inorganic layers as acceptors, and leads to the cohesion of the crystal structure. According to Hirshfeld surface analysis, the highest contributions to the crystal packing are from H⋯H (46.2%), Br⋯H (38.5%), and H⋯O (14.8%) contacts.