Growth of the metal–organic framework ZIF-67 on cellulosic substrates for triboelectric nanogenerators

Metal-organic frameworks (MOFs) are porous crystalline materials with a metal ion coordinated to a ligand molecule. Recently, MOFs are being explored extensively for energy harvesting <i>via</i> triboelectrification. However, the majority of MOFs are brittle and hard to grow, thus leading to poor device stability and flexibility. Herein, the growth of ZIF-67 MOF is achieved on a cellulosic filter paper (CFP) and cotton fabric (CF) separately to use as the active layer in a TENG. The grown ZIF-67 MOFs were used for the fabrication of CFP-TENG and CF-TENG in vertical contact separation mode. The CF-TENG device exhibited a high durability with no significant change in the electrical output for a period of 14 000 s. Additionally, the device generated a maximum electrical output of 60 V and 3 μA with an output power density of 5 mW m^-2 at a load resistance of 800 MΩ. The robustness of the MOF grown on cotton fabric was demonstrated by fabricating a contact separation and rotating TENG device. The rotating TENG device produced an output voltage of ∼100 V and current of 3.5 μA, thus confirming the strong adherence of MOFs on the fabric. The CF-TENG was demonstrated for powering electronics <i>via</i> flexible circuits and for biomechanical energy harvesting by utilising finger tapping, hand tapping, jogging and running movements.