A hydrogen-bridged bis(silylene) complex as a platform for small molecule activation <i>via</i> adjacent metal–ligand cooperation
Effective activation of small molecules (alcohol, phenol, ketones, amine, <i>etc</i>.) by a hydrogen-bridged bis(silylene) complex, which has two adjacent Lewis acidic centers and a hydridic bridging hydrogen with weak Si⋯H bonds, is described, along with product characterization by NMR and X-ray diffraction studies.
Authors
- Hisako Hashimoto (ORCID: https://orcid.org/0000-0001-9649-0857)
- Hiromi Tobita (ORCID: https://orcid.org/0000-0003-3876-050X)
- Yuto Odagiri
- Seiichi Matsuo
Institutions
- Tohoku University (JP)
Publication Details
- Journal
- Dalton Transactions
- Published
- 2024-12-13
- DOI
- https://doi.org/10.1039/d4dt03226h
- Primary Topic
- Organoboron and organosilicon chemistry
- Type
- article
- Field-Weighted Citation Impact
- 0.00
Funders
- Analytical Center for the Government of the Russian Federation
- Japan Society for the Promotion of Science