Peculiarities of Separation of Spin-Phonon Coupling Mechanisms For <sup>23</sup>Na in a NaF Crystal Depending on Temperature and the Number of Paramagnetic Centers

The possibility of changing the efficiency of nuclear spin-phonon coupling by NMR methods using the example of a NaF crystal in a wide temperature range is investigated. To suppress nuclear spin-lattice relaxation involving paramagnetic centers, continuous magnetic saturation at a single Larmor frequency was used instead of acoustic saturation of the 23Na NMR signal at a double frequency. The influence of the color centers induced by gamma irradiation and of temperature on the separation of spin-phonon coupling mechanisms has been studied. No suppression of impurity relaxation was observed for 19F dipole nuclei. It is shown that the suggested magnetic saturation technique for complete or partial shutdown of impurity relaxation of quadrupole nuclei can be implemented on commercial pulse NMR spectrometers.

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Publication Details

Journal
Акустический журнал
Published
2024-09-15
DOI
https://doi.org/10.31857/s0320791924050033
Primary Topic
Solid-state spectroscopy and crystallography
Type
article
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article

Peculiarities of Separation of Spin-Phonon Coupling Mechanisms For 23Na in a NaF Crystal Depending on Temperature and the Number of Paramagnetic Centers

E. V. Charnaya, A. Yu. Serov, V. M. Mikushev, A. M. Rochev
Акустический журнал
Solid-state spectroscopy and crystallography
article

Peculiarities of Separation of Spin-Phonon Coupling Mechanisms For 23Na in a NaF Crystal Depending on Temperature and the Number of Paramagnetic Centers

E. V. Charnaya, A. Yu. Serov, V. M. Mikushev, A. M. Rochev
article en

Abstract

The possibility of changing the efficiency of nuclear spin-phonon coupling by NMR methods using the example of a NaF crystal in a wide temperature range is investigated. To suppress nuclear spin-lattice relaxation involving paramagnetic centers, continuous magnetic saturation at a single Larmor frequency was used instead of acoustic saturation of the 23Na NMR signal at a double frequency. The influence of the color centers induced by gamma irradiation and of temperature on the separation of spin-phonon coupling mechanisms has been studied. No suppression of impurity relaxation was observed for 19F dipole nuclei. It is shown that the suggested magnetic saturation technique for complete or partial shutdown of impurity relaxation of quadrupole nuclei can be implemented on commercial pulse NMR spectrometers.

Акустический журналVol. 70(5)
St Petersburg University (RU)
Affordable and clean energy
Openalex Percentile: Top 85%
Solid-state spectroscopy and crystallography
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