Challenges to the ancient methane seep search strategy: The Bedford Canyon Formation (Middle Jurassic, Santa Ana Mountains, California)

Abstract Carbonates formed by anaerobic oxidation of methane at localized seeps have been recognized in the rock record based on a list of criteria, including anomalous deposition within detrital facies, complex petrofabrics, seep‐endemic macrofauna and 13 C‐depleted isotopic signatures. While much emphasis has been placed on the latter, it is only one of several tools used for identification. This study reports on two different and rare limestone units in the forearc deposits of the Jurassic Bedford Canyon Formation in the Santa Ana Mountains, California (USA). Isolated, metre‐scale limestone pods were found to host abundant endemic Anarhynchia dimerelloid brachiopods and display diverse petrofabrics, including multiple generations of cements. However, the δ 13 C values of the petrofabrics ranged from −14.5 to 4.52‰ Vienna PeeDee Belemnite. These values are only slightly 13 C‐depleted relative to contemporaneous seawater, thus likely recording a stronger component of oceanic dissolved inorganic carbon than hydrocarbons. Additionally, although the petrofabrics are common for seeps (primary micrite, microbialite, pelsparite, intraclastic micrite; early isopachous and botryoidal cements and yellow calcite; late‐stage void‐filling spar), the isotopic values did not follow a predicted trend of increasing δ 13 C with paragenetic sequence. Pelsparite δ 13 C values ranged from −10.65 to −7.09‰ Vienna PeeDee Belemnite while coarse spar and vein cements ranged from −11.42 to −2.44‰ Vienna PeeDee Belemnite. Olistostromes composed of brecciated pelmicrite sourced from shallow fringing‐arc environments are typical of forearc settings. Olistostromes in the Bedford Canyon Formation contain much lower δ 13 C values than the more classically characterized seep deposits, ranging from −21.77 to −10.78‰ Vienna PeeDee Belemnite. While the original shallow‐water source may not have a been a confined seep, the low δ 13 C values require the incorporation of carbon sourced from the oxidation of localized hydrocarbons. Together, these findings recommend a reconsideration of the weight placed on δ 13 C values as the key criterion for distinguishing seeps in the rock record.

Authors

Institutions

Publication Details

Journal
Sedimentology
Published
2024-12-13
DOI
https://doi.org/10.1111/sed.13252
Citations
3
Primary Topic
Methane Hydrates and Related Phenomena
Type
article
Field-Weighted Citation Impact
0.75
Controls
|||
ALL TIME
JAN
FEB
MAR
APR
MAY
JUN
JUL
AUG
SEP
OCT
article

Challenges to the ancient methane seep search strategy: The Bedford Canyon Formation (Middle Jurassic, Santa Ana Mountains, California)

Russell S. Shapiro, Miquela Ingalls
3 citations
Sedimentology
Methane Hydrates and Related Phenomena
0.75
article

Challenges to the ancient methane seep search strategy: The Bedford Canyon Formation (Middle Jurassic, Santa Ana Mountains, California)

Russell S. Shapiro, Miquela Ingalls
article en
3 citations

Abstract

Abstract Carbonates formed by anaerobic oxidation of methane at localized seeps have been recognized in the rock record based on a list of criteria, including anomalous deposition within detrital facies, complex petrofabrics, seep‐endemic macrofauna and 13 C‐depleted isotopic signatures. While much emphasis has been placed on the latter, it is only one of several tools used for identification. This study reports on two different and rare limestone units in the forearc deposits of the Jurassic Bedford Canyon Formation in the Santa Ana Mountains, California (USA). Isolated, metre‐scale limestone pods were found to host abundant endemic Anarhynchia dimerelloid brachiopods and display diverse petrofabrics, including multiple generations of cements. However, the δ 13 C values of the petrofabrics ranged from −14.5 to 4.52‰ Vienna PeeDee Belemnite. These values are only slightly 13 C‐depleted relative to contemporaneous seawater, thus likely recording a stronger component of oceanic dissolved inorganic carbon than hydrocarbons. Additionally, although the petrofabrics are common for seeps (primary micrite, microbialite, pelsparite, intraclastic micrite; early isopachous and botryoidal cements and yellow calcite; late‐stage void‐filling spar), the isotopic values did not follow a predicted trend of increasing δ 13 C with paragenetic sequence. Pelsparite δ 13 C values ranged from −10.65 to −7.09‰ Vienna PeeDee Belemnite while coarse spar and vein cements ranged from −11.42 to −2.44‰ Vienna PeeDee Belemnite. Olistostromes composed of brecciated pelmicrite sourced from shallow fringing‐arc environments are typical of forearc settings. Olistostromes in the Bedford Canyon Formation contain much lower δ 13 C values than the more classically characterized seep deposits, ranging from −21.77 to −10.78‰ Vienna PeeDee Belemnite. While the original shallow‐water source may not have a been a confined seep, the low δ 13 C values require the incorporation of carbon sourced from the oxidation of localized hydrocarbons. Together, these findings recommend a reconsideration of the weight placed on δ 13 C values as the key criterion for distinguishing seeps in the rock record.

SedimentologyVol. 72(2)
Pennsylvania State University (US), California State University, Chico (US)
Life below water
Openalex Percentile: Top 29%
Methane Hydrates and Related Phenomena
0.75
AI Navigator

Ask Laika to Summarize, Analyze, and Connect papers live on the map.

Summarize Papers & Methodologies

Extract key findings, datasets, and comparative methods across publications.

Benchmark Rankings & Visual Analytics

Rank top research institutions, authors, funders, topics, and journals by Field-Weighted Citation Impact (FWCI) and paper volume with instant charts.

Connect Distant Disciplines

Bridge topological clusters on the map to find hidden collaborative intersections.