Onsite ammonia synthesis from water vapor and nitrogen in the air

An innovative method for onsite ammonia synthesis under ambient conditions has been developed using a catalyst mesh composed of magnetite (Fe<sub>3</sub>O<sub>4</sub>) and Nafion polymer. We pass air through the catalyst, which condenses microdroplets from atmospheric water vapor and uses nitrogen from the air, resulting in ammonia concentrations ranging from 25 to 120 μM in 1 hour, depending on local relative humidity. Operated at room temperature and atmospheric pressure, this technique eliminates the need for additional electricity or radiation, thereby substantially reducing carbon dioxide emissions compared to the traditional Haber-Bosch process. In laboratory experiments, we further optimized the reaction conditions and scaled up the process. After 2 hours of spraying, the ammonia concentration increased to 270.2 ± 25.1 μM. In addition, we present a portable device designed for onsite ammonia production which consistently produces an ammonia concentration that is adequate for some agricultural irrigation purposes.

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Publication Details

Journal
Science Advances
Published
2024-12-13
DOI
https://doi.org/10.1126/sciadv.ads4443
Citations
32
Primary Topic
Ammonia Synthesis and Nitrogen Reduction
Type
article
Field-Weighted Citation Impact
3.42

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article

Onsite ammonia synthesis from water vapor and nitrogen in the air

Jinheng Xu, Richard N. Zare, Xiaowei Song, Chanbasha Basheer
32 citations
Science Advances
Ammonia Synthesis and Nitrogen Reduction
3.42
article

Onsite ammonia synthesis from water vapor and nitrogen in the air

Jinheng Xu, Richard N. Zare, Xiaowei Song, Chanbasha Basheer
article en
32 citations

Abstract

An innovative method for onsite ammonia synthesis under ambient conditions has been developed using a catalyst mesh composed of magnetite (Fe<sub>3</sub>O<sub>4</sub>) and Nafion polymer. We pass air through the catalyst, which condenses microdroplets from atmospheric water vapor and uses nitrogen from the air, resulting in ammonia concentrations ranging from 25 to 120 μM in 1 hour, depending on local relative humidity. Operated at room temperature and atmospheric pressure, this technique eliminates the need for additional electricity or radiation, thereby substantially reducing carbon dioxide emissions compared to the traditional Haber-Bosch process. In laboratory experiments, we further optimized the reaction conditions and scaled up the process. After 2 hours of spraying, the ammonia concentration increased to 270.2 ± 25.1 μM. In addition, we present a portable device designed for onsite ammonia production which consistently produces an ammonia concentration that is adequate for some agricultural irrigation purposes.

Science AdvancesVol. 10(50)
King Fahd University of Petroleum and Minerals (SA), Stanford University (US)
Multidisciplinary University Research Initiative, Air Force Office of Scientific Research
Clean water and sanitation
Openalex Percentile: Top 6%
Ammonia Synthesis and Nitrogen Reduction
3.42
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