Synergistic photocatalysis enables aerobic oxo-hydrazination of α-diazoacetates with azobenzenes
A photocatalytic oxo-hydrazination of α-diazoacetates with azobenzenes has been developed. With air as an oxygen source, the reaction proceeded smoothly and afforded previously unknown <i>N</i>,<i>N</i>'-diarylhydrazino-containing oxoacetates. Mechanistically, the reaction is enabled by cooperation of photoredox catalysis, energy transfer photocatalysis and direct photoexcitation.
Authors
- Jingya Yang (ORCID: https://orcid.org/0000-0002-7419-5133)
- Hongyan Zhou (ORCID: https://orcid.org/0000-0003-0446-8404)
- Weihua Ma (ORCID: https://orcid.org/0000-0002-5052-3884)
- Yating Han
- Qi Dong (ORCID: https://orcid.org/0000-0002-3502-9095)
- Sheng-Yu Wang (ORCID: https://orcid.org/0000-0001-8354-4422)
Institutions
- Gansu Agricultural University (CN)
- Northwest Normal University (CN)
Publication Details
- Journal
- Chemical Communications
- Published
- 2024-12-12
- DOI
- https://doi.org/10.1039/d4cc05668j
- Citations
- 7
- Primary Topic
- Cyclopropane Reaction Mechanisms
- Type
- article
- Field-Weighted Citation Impact
- 1.75