N skeleton-regulated cobalt phthalocyanine promotes polysulfide adsorption and redox kinetics

An N skeleton substituent on cobalt phthalocyanine (CoPc) was meticulously studied to redistribute the charge in phthalocyanine, improve the mass diffusion, and promote the redox kinetics of polysulfides (LiPS), resulting in a significant ultra-low capacity decay of 0.11% at 5C over 500 cycles.

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Publication Details

Journal
Chemical Communications
Published
2024-12-12
DOI
https://doi.org/10.1039/d4cc05742b
Primary Topic
Fuel Cells and Related Materials
Type
article
Field-Weighted Citation Impact
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article

N skeleton-regulated cobalt phthalocyanine promotes polysulfide adsorption and redox kinetics

Zhanwei Xu, Kai Yao, Jiayin Li, Zhi Li et al.
Chemical Communications
Fuel Cells and Related Materials
article

N skeleton-regulated cobalt phthalocyanine promotes polysulfide adsorption and redox kinetics

Zhanwei Xu, Kai Yao, Jiayin Li, Zhi Li, Liang Li, Yinan Zhang, Jiaqi Zhao, Hang Niu
article en

Abstract

An N skeleton substituent on cobalt phthalocyanine (CoPc) was meticulously studied to redistribute the charge in phthalocyanine, improve the mass diffusion, and promote the redox kinetics of polysulfides (LiPS), resulting in a significant ultra-low capacity decay of 0.11% at 5C over 500 cycles.

Chemical CommunicationsVol. 61(8)
University of Alberta (CA), Forschungszentrum Jülich (DE), Beijing Chaoyang Emergency Medical Center (CN), Shaanxi University of Science and Technology (CN)
Clean water and sanitation
Openalex Percentile: Top 80%
Fuel Cells and Related Materials
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