Association of Zn- and Mg-based chain transfer agents in coordinative chain transfer polymerizations of olefins for enhanced control and activity
ZnEt 2 is used for the first time as a reversible transfer agent in olefin polymerization with a neodymium metallocene catalyst. Its presence has improved the catalyst's performance for the coordinative chain transfer polymerization of ethylene.
Authors
- Franck D’Agosto (ORCID: https://orcid.org/0000-0003-2730-869X)
- Nicolas Baulu
- Ludmilla Verrieux
- Robert Ngo
- Christophe Boisson (ORCID: https://orcid.org/0000-0002-7909-901X)
- Lionel Perrin (ORCID: https://orcid.org/0000-0002-0702-8749)
- Ariane Desgranges
- F. Jean-Baptiste-Dit-Dominique
- Victor Lancenet
Institutions
- Université Claude Bernard Lyon 1 (FR)
- Centre National de la Recherche Scientifique (FR)
- Michelin (France) (FR)
- Institut de Chimie et Biochimie Moléculaires et Supramoléculaires (FR)
- École d'Ingénieurs en Chimie et Sciences du Numérique (FR)
Publication Details
- Journal
- Polymer Chemistry
- Published
- 2024-12-12
- DOI
- https://doi.org/10.1039/d4py01220h
- Citations
- 1
- Primary Topic
- Advanced Polymer Synthesis and Characterization
- Type
- article
- Field-Weighted Citation Impact
- 0.25