Electrochemically driven Michael reaction: synthesis of hydroquinone thioethers

An original method for the synthesis of a diverse array of hydroquinone thioethers with yields of 36% to 99% under mild conditions is described. The process is voltammetrically controlled and involves electrogenerating active protonated <i>p</i>-quinone followed by thiol addition.

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Publication Details

Journal
Organic & Biomolecular Chemistry
Published
2024-12-12
DOI
https://doi.org/10.1039/d4ob01886a
Primary Topic
Sulfur-Based Synthesis Techniques
Type
article
Field-Weighted Citation Impact
0.00
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article

Electrochemically driven Michael reaction: synthesis of hydroquinone thioethers

Vladimir A. Kokorekin, Igor V. Trushkov, Natalia Moiseeva, Andrey N. Sokolov
Organic & Biomolecular Chemistry
Sulfur-Based Synthesis Techniques
article

Electrochemically driven Michael reaction: synthesis of hydroquinone thioethers

Vladimir A. Kokorekin, Igor V. Trushkov, Natalia Moiseeva, Andrey N. Sokolov
article en

Abstract

An original method for the synthesis of a diverse array of hydroquinone thioethers with yields of 36% to 99% under mild conditions is described. The process is voltammetrically controlled and involves electrogenerating active protonated <i>p</i>-quinone followed by thiol addition.

Organic & Biomolecular ChemistryVol. 23(5)
Sechenov University (RU), N.D. Zelinsky Institute of Organic Chemistry (RU)
Openalex Percentile: Top 83%
Sulfur-Based Synthesis Techniques
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