On the Exact Solution for the Schrödinger Equation

For almost 75 years, the general solution for the Schrödinger equation was assumed to be generated by an exponential or a time-ordered exponential known as the Dyson series. We study the unitarity of a solution in the case of a singular Hamiltonian and provide a new methodology that is not based on the assumption that the underlying space is L2(R). Then, an alternative operator for generating the time evolution that is manifestly unitary is suggested, regardless of the choice of Hamiltonian. The new construction involves an additional positive operator that normalizes the wave function locally and allows us to preserve unitarity, even when dealing with infinite dimensional or non-normed spaces. Our considerations show that Schrödinger and Liouville equations are, in fact, two sides of the same coin and together they provide a unified description for unbounded quantum systems.

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Particles
Published
2024-12-12
DOI
https://doi.org/10.3390/particles7040067
Primary Topic
Spectral Theory in Mathematical Physics
Type
article
Field-Weighted Citation Impact
0.00

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article

On the Exact Solution for the Schrödinger Equation

Yair Mulian
Particles
Spectral Theory in Mathematical Physics
article

On the Exact Solution for the Schrödinger Equation

Yair Mulian
article en

Abstract

For almost 75 years, the general solution for the Schrödinger equation was assumed to be generated by an exponential or a time-ordered exponential known as the Dyson series. We study the unitarity of a solution in the case of a singular Hamiltonian and provide a new methodology that is not based on the assumption that the underlying space is L2(R). Then, an alternative operator for generating the time evolution that is manifestly unitary is suggested, regardless of the choice of Hamiltonian. The new construction involves an additional positive operator that normalizes the wave function locally and allows us to preserve unitarity, even when dealing with infinite dimensional or non-normed spaces. Our considerations show that Schrödinger and Liouville equations are, in fact, two sides of the same coin and together they provide a unified description for unbounded quantum systems.

ParticlesVol. 7(4)
Chinese Academy of Sciences (CN), Universidade de Santiago de Compostela (ES), Institute of Modern Physics (CN), University of Chinese Academy of Sciences (CN)
Chinese Academy of Sciences
Openalex Percentile: Top 62%
Spectral Theory in Mathematical Physics
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