Solvent and counterion cooperatively induced inversion of the stereocenter Δ/Λ and CPL in a mononuclear Eu(<scp>iii</scp>) complex
The mononuclear Eu 3+ complexes show solvent and Cs + ion cooperatively induced metal stereocenter Δ/Λ configurational inversion, accompanied by an inversion of the circularly polarized luminescence sign.
Authors
- Yanyan Zhou (ORCID: https://orcid.org/0000-0001-6504-4205)
- Ting Gao (ORCID: https://orcid.org/0000-0002-6981-1886)
- Ziye Song (ORCID: https://orcid.org/0009-0006-9769-0352)
- Pengfei Yan (ORCID: https://orcid.org/0000-0001-6387-7502)
- Hongfeng Li (ORCID: https://orcid.org/0000-0003-4646-0515)
- Sen Yin (ORCID: https://orcid.org/0000-0003-4123-3436)
- Wenhua Li (ORCID: https://orcid.org/0000-0003-0257-7252)
Institutions
- Heilongjiang University (CN)
Publication Details
- Journal
- Inorganic Chemistry Frontiers
- Published
- 2024-12-11
- DOI
- https://doi.org/10.1039/d4qi02730b
- Citations
- 3
- Primary Topic
- Molecular spectroscopy and chirality
- Type
- article
- Field-Weighted Citation Impact
- 0.72