Empowering Tri‐Functional Palladium's Catalytic Activity and Durability in Electrocatalytic Formic Acid Oxidation Reaction via Innovative Self‐Caging and Alloying Strategies (Adv. Sci. 46/2024)
Formic Acidic oxidAtion reActionIn article number 2405725, Taeseup Song, Tae Ho Shin, HyukSu Han, and co-workers develop a novel nanomaterial engineering approach to design a self-caged and alloyed Pd-based electrocatalyst that demonstrates exceptional durability and activity for formic acid oxidation reaction.A conductive carbon frame embedded with Pd-Zr alloyed nanoparticles can be formed by utilizing a metal-organic framework (MOF) as a precursor.The self-caging and alloying process occurs in situ during electrochemical reactions.This enables the encapsulation of Pd-Zr particles within neighboring frames effectively mitigating particle aggregation and consequential enhancing catalytic performance.
Authors
- Min Su Cho (ORCID: https://orcid.org/0000-0002-9372-6796)
- Ghulam Ali (ORCID: https://orcid.org/0000-0003-2815-6667)
- HyukSu Han (ORCID: https://orcid.org/0000-0001-7230-612X)
- Taeseup Song (ORCID: https://orcid.org/0000-0002-1174-334X)
- Seoyoon Shin
- Arpan Kumar Nayak (ORCID: https://orcid.org/0000-0002-8864-813X)
- Tae Ho Shin (ORCID: https://orcid.org/0000-0002-9001-7863)
- Mingony Kim (ORCID: https://orcid.org/0000-0001-9761-388X)
- Gyeom Seong Jeon (ORCID: https://orcid.org/0009-0007-4798-9791)
- Kyung Yoon Chung (ORCID: https://orcid.org/0000-0002-1273-746X)
- Jeong Ho Ryu (ORCID: https://orcid.org/0000-0002-5662-5136)
- Ashish Gaur (ORCID: https://orcid.org/0009-0000-1136-4764)
- Chan‐Woo Lee (ORCID: https://orcid.org/0000-0002-0567-0527)
- Jiseok Kwon (ORCID: https://orcid.org/0000-0003-0145-658X)
- Sun Young Jung
Publication Details
- Journal
- Advanced Science
- Published
- 2024-12-01
- DOI
- https://doi.org/10.1002/advs.202470283
- Primary Topic
- Oxidative Organic Chemistry Reactions
- Type
- article
- Field-Weighted Citation Impact
- 0.00