An Energy‐Tunable Dual Emission Mechanism of the Hybridized Local and Charge Transfer (HLCT) and the Excited State Conjugation Enhancement (ESCE)

Molecular design of dual-fluorescent probes requires precise adjustment of the energy levels of two excited states and the energy barrier between them. While the hybridized local and charge-transfer (HLCT) state has been recently focused as an important excited state for high emission efficiency with a tunable energy level, a dual emission involving the HLCT state has been only achieved with the excited-state intramolecular proton transfer (ESIPT) system. Here, a series of dual-fluorescent molecules involving an HLCT excited state with the excited-state conjugation enhancement (ESCE) motif is presented as the first case. The energy level of the HLCT state has been adjusted by changing substituents and solvents, separately from the ESCE energy level. The HLCT-ESCE molecular design with tunable fluorescence properties proposes a new strategy for the development of advanced fluorescent probes.