<i>E</i>→<i>Z contra</i>-Thermodynamic isomerization of alkenes with SEGPHOS
Herein we disclose a photosensitized <i>E</i>→<i>Z contra</i>-thermodynamic isomerization of vinyl sulfones, employing SEGPHOS as a promoter. The reaction was performed successfully on 23 vinyl sulfones and was extended to three other olefins. Different mechanistic experiments were performed as well as photophysical studies.
Authors
- Thomas Poisson (ORCID: https://orcid.org/0000-0002-0503-9620)
- Philippe Jubault (ORCID: https://orcid.org/0000-0002-3295-9326)
- Margaux Riomet (ORCID: https://orcid.org/0000-0002-3444-5652)
Institutions
- Centre National de la Recherche Scientifique (FR)
- Normandie Université (FR)
- Laboratoire COBRA (FR)
- Université de Rouen Normandie (FR)
- Institut National des Sciences Appliquées Rouen Normandie (FR)
Publication Details
- Journal
- Chemical Communications
- Published
- 2024-12-11
- DOI
- https://doi.org/10.1039/d4cc04889j
- Citations
- 1
- Primary Topic
- Sulfur-Based Synthesis Techniques
- Type
- article
- Field-Weighted Citation Impact
- 0.25
Funders
- Indian National Science Academy
- European Commission
- Agence Nationale de la Recherche
- Centre National de la Recherche Scientifique
- Université de Rouen
- Institut National des Sciences Appliquées Rouen
- Normandie Université
- Région Normandie
- Horizon 2020 Framework Programme
- European Regional Development Fund