Effect of the 1D/2D dimensionality in copper and silver thiolate coordination polymers on their photophysical properties
A series of four new copper and silver-thiolate, [M(<i>m</i>-SPhCO<sub>2</sub>R)]<sub><i>n</i></sub> (M = Cu, Ag and R = H, Me), coordination polymers is reported. The study shows that the hydrogen bonding between the carboxylic acids directs the formation of a 2D structure associated with poor photoemission, while the steric hindrance of the ester groups allows the assembly of a 1D network coupled with bright luminescence.
Authors
- Gilles Ledoux (ORCID: https://orcid.org/0000-0002-0867-1285)
- Adel Mesbah (ORCID: https://orcid.org/0000-0002-6905-2402)
- Erwann Jeanneau (ORCID: https://orcid.org/0000-0002-8861-4140)
- Miguel Monge (ORCID: https://orcid.org/0000-0002-9672-8279)
- Alexandra Fateeva (ORCID: https://orcid.org/0000-0003-3805-6571)
- Saly Hawila
- Oleksandra Veselska (ORCID: https://orcid.org/0000-0002-5709-1906)
- Florent Perret (ORCID: https://orcid.org/0000-0003-1413-6374)
- Aude Demessence (ORCID: https://orcid.org/0000-0002-8690-5489)
- S. Pailhès (ORCID: https://orcid.org/0000-0002-9221-7092)
- Ahmad Abdallah
- Nathalie Guillou (ORCID: https://orcid.org/0009-0003-4373-4063)
- Chloé Andrade
- Alexis Giraudon
Institutions
- Université Claude Bernard Lyon 1 (FR)
- Centre National de la Recherche Scientifique (FR)
- Universidad de La Rioja (ES)
- Université de Versailles Saint-Quentin-en-Yvelines (FR)
- Université Paris-Saclay (FR)
- Institut de Chimie et Biochimie Moléculaires et Supramoléculaires (FR)
- Institut de Recherches sur la Catalyse et l'Environnement de Lyon (FR)
- Czech Technical University in Prague (CZ)
Publication Details
- Journal
- Chemical Communications
- Published
- 2024-12-11
- DOI
- https://doi.org/10.1039/d4cc06171c
- Citations
- 3
- Primary Topic
- Nanocluster Synthesis and Applications
- Type
- article
- Field-Weighted Citation Impact
- 0.35
Funders
- Agence Nationale de la Recherche
- European Regional Development Fund