Surface Engineering of 2D Metal‐Porphyrin Metal–Organic Frameworks Z‐Scheme Heterostructure for Boosting and Stable Photocatalytic Hydrogen Evolution

How to improve the stability and activity of metal-organic frameworks is an attractive but challenging task in energy conversion and pollutant degradation of metal-organic frameworks materials. In this paper, we developed a facile method by fabricating TiO₂ nanoparticles (NPs) layer on 2D copper tetracarboxylphenyl-metalloporphyrin metal-organic frameworks (MOFs) with Zn2+ as the linkers (ZnTCuMT-X, "Zn" represented Zn2+ as the linkers, the first "T" represented tetracarboxylphenyl-metalloporphyrin (TCPP), "Cu" represented the Cu2+ coordinated into the porphyrin macrocycle, "M" represented MOFs, the second "T" represented TiO₂ NPs layer, and "X" represented the added volume of n-tetrabutyl titanate (X = 100, 200, 300 or 400)). It was found that the optimized ZnTCuMT-200 showed greatly and stably enhanced H2 generation, which was about 28.2 times and 47.0 times as high as those of the original metalloporphyrin MOFs and TiO₂, respectively. Combined with the results of free radical capture, X-ray photoelectron spectra, electron spin resonance and theoretical calculation, a direct Z-scheme electron transfer mechanism was achieved to fully explain the enhanced photocatalytic performance. It demonstrates that facilely designing Z-scheme heterostructures based on porphyrin MOFs modified with inorganic semiconductor layer could be an advantageous strategy for enhancing the stability and activity of photocatalytic hydrogen evolution.