Polyoxometalates as advanced-performance anions for ∼<i>D</i><sub>5h</sub> Dy(<scp>iii</scp>) single-ion magnets
We enhance single-ion magnet (SIM) magnetisation reversal barriers by engineering the second coordination sphere, substituting conventional small monoanions with a bulky polyoxometalate (POM) trianion. Importantly, our approach serves as a model for creating new high-performance multifunctional hybrid materials.
Authors
- Mark Murrie (ORCID: https://orcid.org/0000-0001-7297-2878)
- Claire Wilson (ORCID: https://orcid.org/0000-0002-0090-5374)
- Angelos B. Canaj
Institutions
- University of Glasgow (GB)
Publication Details
- Journal
- Dalton Transactions
- Published
- 2024-12-10
- DOI
- https://doi.org/10.1039/d4dt02877e
- Citations
- 3
- Primary Topic
- Magnetism in coordination complexes
- Type
- article
- Field-Weighted Citation Impact
- 0.35
Funders
- University of Southampton
- Engineering and Physical Sciences Research Council