Electrochemical Oxidative Hydroxychalcogenation of Olefins with Disulfides/Thiols/Diselenides and H<sub>2</sub>O as Nucleophilic Oxygen Sources
Abstract A direct electrochemical redox reaction of olefins and disulfides/thiols/diselenides without external oxidants has been developed, which includes the hydroxychalcogenation of olefins. This procedure exhibited good functional group tolerance, and a series of β ‐hydroxysulfide/ β ‐hydroxyselenide derivatives were obtained in moderate to good yields. Mechanistic studies and cyclic voltammetry were also conducted to elucidate the reaction process.
Authors
- Man Miao
- Zhenyu An (ORCID: https://orcid.org/0000-0002-1595-2077)
- Huachao Li
- Xiaobing Lan
- J. Li (ORCID: https://orcid.org/0009-0004-6664-2492)
- Jian Zhang (ORCID: https://orcid.org/0000-0002-6558-791X)
- Pengpeng Liu (ORCID: https://orcid.org/0000-0002-2335-7075)
- Wenxue Li (ORCID: https://orcid.org/0000-0002-7308-7827)
- Rui Wang (ORCID: https://orcid.org/0000-0001-9569-8613)
- Fengkai Sun (ORCID: https://orcid.org/0000-0003-1492-3474)
- Jian‐Qiang Yu (ORCID: https://orcid.org/0009-0001-0001-8919)
Institutions
- Shanghai Jiao Tong University (CN)
- Ningxia University (CN)
- Ningxia Medical University (CN)
Publication Details
- Journal
- European Journal of Organic Chemistry
- Published
- 2024-12-10
- DOI
- https://doi.org/10.1002/ejoc.202401226
- Citations
- 4
- Primary Topic
- Sulfur-Based Synthesis Techniques
- Type
- article
- Field-Weighted Citation Impact
- 1.00