Design of a Renewable Methanol Production Process from Biogas: Analysis of the Influence of the Operating Pressure in the Synthesis Loop
This study presents the design and analysis of an energy-integrated process for producing green methanol from biogas. Emphasizing the need for sustainable fuel solutions, the paper explores the use of biogas, purified to biomethane, as a feedstock for methanol synthesis. The process involves a convective reformer with bayonet-type tubes for syngas production and a multitubular methanol synthesis reactor. The integration of thermal energy is a core feature, ensuring the process is self-sufficient. Key aspects analyzed include the impact of methanol synthesis loop pressure (30–90 bar) on performance metrics such as carbon and energy efficiency and CAPEX/OPEX of the loop. An optimum operating pressure of 40 bar was found. Simulation results indicate high methane conversion in the reformer (87.34%) and effective internal heat recovery due to the bayonet-type tubes (19%). The overall process achieves a carbon efficiency of 48.5% and an energy efficiency of around 64%.
Authors
- Eduardo M. Izurieta (ORCID: https://orcid.org/0000-0002-7012-3992)
- María Victoria Del Pópolo Grzona
- Eduardo Rivera López
- Marisa N. Pedernera
Institutions
- Consejo Nacional de Investigaciones Científicas y Técnicas (AR)
- Planta Piloto de Ingeniería Química (AR)
- Universidad Nacional del Sur (AR)
Publication Details
- Journal
- Industrial & Engineering Chemistry Research
- Published
- 2024-12-10
- DOI
- https://doi.org/10.1021/acs.iecr.4c03170
- Citations
- 3
- Primary Topic
- Catalysts for Methane Reforming
- Type
- article
- Field-Weighted Citation Impact
- 0.32
Funders
- Consejo Nacional de Investigaciones Científicas y Técnicas
- Universidad Nacional del Sur
- Agencia Nacional de Promoción de la Investigación, el Desarrollo Tecnológico y la Innovación