Design of a Renewable Methanol Production Process from Biogas: Analysis of the Influence of the Operating Pressure in the Synthesis Loop

This study presents the design and analysis of an energy-integrated process for producing green methanol from biogas. Emphasizing the need for sustainable fuel solutions, the paper explores the use of biogas, purified to biomethane, as a feedstock for methanol synthesis. The process involves a convective reformer with bayonet-type tubes for syngas production and a multitubular methanol synthesis reactor. The integration of thermal energy is a core feature, ensuring the process is self-sufficient. Key aspects analyzed include the impact of methanol synthesis loop pressure (30–90 bar) on performance metrics such as carbon and energy efficiency and CAPEX/OPEX of the loop. An optimum operating pressure of 40 bar was found. Simulation results indicate high methane conversion in the reformer (87.34%) and effective internal heat recovery due to the bayonet-type tubes (19%). The overall process achieves a carbon efficiency of 48.5% and an energy efficiency of around 64%.

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Publication Details

Journal
Industrial & Engineering Chemistry Research
Published
2024-12-10
DOI
https://doi.org/10.1021/acs.iecr.4c03170
Citations
3
Primary Topic
Catalysts for Methane Reforming
Type
article
Field-Weighted Citation Impact
0.32

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article

Design of a Renewable Methanol Production Process from Biogas: Analysis of the Influence of the Operating Pressure in the Synthesis Loop

Eduardo M. Izurieta, María Victoria Del Pópolo Grzona, Eduardo Rivera López, Marisa N. Pedernera
3 citations
Industrial & Engineering Chemistry Research
Catalysts for Methane Reforming
0.32
article

Design of a Renewable Methanol Production Process from Biogas: Analysis of the Influence of the Operating Pressure in the Synthesis Loop

Eduardo M. Izurieta, María Victoria Del Pópolo Grzona, Eduardo Rivera López, Marisa N. Pedernera
article en
3 citations

Abstract

This study presents the design and analysis of an energy-integrated process for producing green methanol from biogas. Emphasizing the need for sustainable fuel solutions, the paper explores the use of biogas, purified to biomethane, as a feedstock for methanol synthesis. The process involves a convective reformer with bayonet-type tubes for syngas production and a multitubular methanol synthesis reactor. The integration of thermal energy is a core feature, ensuring the process is self-sufficient. Key aspects analyzed include the impact of methanol synthesis loop pressure (30–90 bar) on performance metrics such as carbon and energy efficiency and CAPEX/OPEX of the loop. An optimum operating pressure of 40 bar was found. Simulation results indicate high methane conversion in the reformer (87.34%) and effective internal heat recovery due to the bayonet-type tubes (19%). The overall process achieves a carbon efficiency of 48.5% and an energy efficiency of around 64%.

Industrial & Engineering Chemistry ResearchVol. 63(51)
Consejo Nacional de Investigaciones Científicas y Técnicas (AR), Planta Piloto de Ingeniería Química (AR), Universidad Nacional del Sur (AR)
Consejo Nacional de Investigaciones Científicas y Técnicas, Universidad Nacional del Sur, Agencia Nacional de Promoción de la Investigación, el Desarrollo Tecnológico y la Innovación
Affordable and clean energy
Openalex Percentile: Top 52%
Catalysts for Methane Reforming
0.32
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