Easily synthesized soybean oil bio-based material for wastewater treatment
The need for alternative petroleum-based polymers sheds light on developing new biomaterials, even though their synthesis frequently has an enormous environmental impact. Hence, a new synthetic approach to prepare simple soybean oil (SO) derived materials is here proposed to decrease the polymerization impact. Fresh and expired SO are used as starting materials, and a solid gummy material is obtained using BF 3 as catalyst in just 1 h with microwave irradiation. A combined approach of 1 H NMR, GC–MS, and ATR-FTIR analyses enabled an understanding of the principal role of the fatty acids' unsaturation on the cross-linking reaction. The material was characterized through SEM, DSC, nanotomography and XRD analyses, revealing a compact morphology with some cavities. The material was, then, applied as adsorbent for some wastewater pollutants. Adsorption efficiencies of the bio-based material for different organic solvents or dye water solution were analysed, obtaining good efficiencies. Moreover, the material can be recycled after pollutant adsorption and used several times. Finally, it can be chemically degraded and is biocompatible, expanding the application of this bio-based material also to other fields. • A new environmental-friendly approach to synthetize Soybean Oil-derived materials is proposed. • The material is fully characterized and applied as adsorbent for wastewater pollutants. • The biobased material is recyclable after pollutant adsorption, chemically degradable and biocompatible.
Authors
- Filippo Vitale (ORCID: https://orcid.org/0000-0002-6776-9821)
- Elena Piacenza (ORCID: https://orcid.org/0000-0003-1929-1031)
- Sara Amata (ORCID: https://orcid.org/0009-0005-8263-4633)
- Carla Rizzo (ORCID: https://orcid.org/0000-0002-5157-1773)
- Viviana Barra (ORCID: https://orcid.org/0000-0002-7186-4485)
- Silvestre Buscemi (ORCID: https://orcid.org/0000-0002-0643-5254)
- Delia Francesca Chillura Martino (ORCID: https://orcid.org/0000-0001-5141-7285)
- Antonio Palumbo Piccionello (ORCID: https://orcid.org/0000-0003-4402-5798)
- Salvatore Martino
Institutions
- University of Copenhagen (DK)
- Institute of Biophysics (BG)
- University of Palermo (IT)
Publication Details
- Journal
- Sustainable materials and technologies
- Published
- 2024-12-11
- DOI
- https://doi.org/10.1016/j.susmat.2024.e01216
- Citations
- 1
- Primary Topic
- biodegradable polymer synthesis and properties
- Type
- article
- Field-Weighted Citation Impact
- 0.17
Funders
- Ministero dell’Istruzione, dell’Università e della Ricerca
- Università degli Studi di Palermo