Computational studies on Mn(<scp>iii</scp>)-catalyzed cyclopropanols: a case of Mn(<scp>iii</scp>)-based metalloradical catalysis involving an α-Mn(<scp>ii</scp>)-bound-alkyl radical key intermediate
Substrates that generate metal-bound radical species have predominantly been oxidative in nature. In this study, we present cyclopropanol, a reducing substrate, capable of generating metal-bound radicals through a Mn(acac) 3 catalyst.
Authors
- Long‐Wu Ye (ORCID: https://orcid.org/0000-0003-3108-2611)
- Xin Lu (ORCID: https://orcid.org/0000-0003-4722-1137)
- Yidong Luo
- Xiuyuan Zou (ORCID: https://orcid.org/0009-0000-6600-0298)
- Hong Pan (ORCID: https://orcid.org/0000-0002-2973-8039)
- Qing Sun (ORCID: https://orcid.org/0000-0003-1630-9224)
- Pengcheng Zhang (ORCID: https://orcid.org/0009-0002-6198-7999)
Institutions
- Xiamen University (CN)
- Zhoukou Normal University (CN)
- Institute of New Materials (CN)
- Nanchang Hangkong University (CN)
Publication Details
- Journal
- Organic Chemistry Frontiers
- Published
- 2024-12-11
- DOI
- https://doi.org/10.1039/d4qo01775g
- Primary Topic
- Oxidative Organic Chemistry Reactions
- Type
- article
- Field-Weighted Citation Impact
- 0.00