A sandwich-like heterometallic Fe<sub>7</sub>Sn<sub>6</sub> oxo cluster constructed by tessellation of an Anderson-like {Fe<sub>7</sub>} wheel for near-infrared photothermal conversion
Herein we report a unique sandwich-like heterometallic Fe7Sn6 oxo cluster, which features an Anderson-type {Fe<sub>7</sub>} wheel sandwiched by two {Sn<sub>3</sub>} layers and is formed <i>via</i> the coordination-induced effect of 2,6-pyridinedicarboxylate. The highly efficient photothermal conversion capability and excellent photothermal stability of Fe7Sn6 demonstrate the potential for solar energy conversion.
Authors
- Xiu-Juan Tian
- Xian‐Ming Zhang (ORCID: https://orcid.org/0000-0002-8809-3402)
- Shi-Li Li (ORCID: https://orcid.org/0000-0002-5598-7418)
- Qian Lu (ORCID: https://orcid.org/0000-0001-6972-6537)
Institutions
- Ministry of Education (RW)
- Taiyuan University of Science and Technology (CN)
- Taiyuan University of Technology (CN)
Publication Details
- Journal
- Chemical Communications
- Published
- 2024-12-10
- DOI
- https://doi.org/10.1039/d4cc05796a
- Citations
- 2
- Primary Topic
- Nanocluster Synthesis and Applications
- Type
- article
- Field-Weighted Citation Impact
- 0.23