Sn(SO<sub>4</sub>)<sub>2</sub>·2H<sub>2</sub>O from synchrotron powder data

Tin(IV) sulfate dihydrate, Sn(SO<sub>4</sub>)<sub>2</sub>·2H<sub>2</sub>O, was prepared in a reflux of sulfuric acid under oxidizing conditions. Its crystal structure was determined from powder synchrotron X-ray diffraction data and is constructed of (100) layers of [SnO<sub>4</sub>(H<sub>2</sub>O)<sub>2</sub>] octa-hedra (point group symmetry 1) corner-connected by sulfate tetra-hedra. Hydrogen bonds of moderate strength between the water mol-ecules and sulfate O atoms hold the layers together.

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IUCrData
Published
2024-12-10
DOI
https://doi.org/10.1107/s2414314624011799
Citations
1
Primary Topic
X-ray Diffraction in Crystallography
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article
Field-Weighted Citation Impact
0.12

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article

Sn(SO4)2·2H2O from synchrotron powder data

Øystein S. Fjellvåg, Helmer Fjellvåg
1 citations
IUCrData
X-ray Diffraction in Crystallography
0.12
article

Sn(SO4)2·2H2O from synchrotron powder data

Øystein S. Fjellvåg, Helmer Fjellvåg
article en
1 citations

Abstract

Tin(IV) sulfate dihydrate, Sn(SO<sub>4</sub>)<sub>2</sub>·2H<sub>2</sub>O, was prepared in a reflux of sulfuric acid under oxidizing conditions. Its crystal structure was determined from powder synchrotron X-ray diffraction data and is constructed of (100) layers of [SnO<sub>4</sub>(H<sub>2</sub>O)<sub>2</sub>] octa-hedra (point group symmetry 1) corner-connected by sulfate tetra-hedra. Hydrogen bonds of moderate strength between the water mol-ecules and sulfate O atoms hold the layers together.

IUCrDataVol. 9(12)
University of Oslo (NO), Institute for Energy Technology (NO), Norsk Hydro (Norway) (NO)
European Synchrotron Radiation Facility, Norges Forskningsråd
Clean water and sanitation
Openalex Percentile: Top 57%
X-ray Diffraction in Crystallography
0.12
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