A heterobimetallic MOF as a stable heterogeneous catalyst with high activity for ethylene oligomerization

Herein, the performance of heterobimetallic clusters MOF-1213(Dy/Ni) for ethylene oligomerization reactions was investigated. At 30 °C and 40 bar, its average ethylene turnover frequency is approximately 160 000 h<sup>-1</sup> (α-olefins selectivity above 80%), which was higher than the activity previously reported for most heterogeneous catalysts under similar conditions.

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Publication Details

Journal
Chemical Communications
Published
2024-12-10
DOI
https://doi.org/10.1039/d4cc05296j
Citations
2
Primary Topic
Metal-Organic Frameworks: Synthesis and Applications
Type
article
Field-Weighted Citation Impact
0.32
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article

A heterobimetallic MOF as a stable heterogeneous catalyst with high activity for ethylene oligomerization

Gang Li, Cong Wang, Anfeng Peng, Zheng Huang
2 citations
Chemical Communications
Metal-Organic Frameworks: Synthesis and Applications
0.32
article

A heterobimetallic MOF as a stable heterogeneous catalyst with high activity for ethylene oligomerization

Gang Li, Cong Wang, Anfeng Peng, Zheng Huang
article en
2 citations

Abstract

Herein, the performance of heterobimetallic clusters MOF-1213(Dy/Ni) for ethylene oligomerization reactions was investigated. At 30 °C and 40 bar, its average ethylene turnover frequency is approximately 160 000 h<sup>-1</sup> (α-olefins selectivity above 80%), which was higher than the activity previously reported for most heterogeneous catalysts under similar conditions.

Chemical CommunicationsVol. 61(5)
Dalian University of Technology (CN), Dalian University (CN)
Openalex Percentile: Top 47%
Metal-Organic Frameworks: Synthesis and Applications
0.32
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