Stabilization of an Aqueous Solution of a Liquid Micro Fertilizer Containing Trilon B as a Chelating Agent. Structure of the Molecular Crystal of Sodium Carbamide Ethylenediaminetetraacetate Hydrate NaH3L1·(H2N)2CO·H2O

Chemical analysis methods were used to identify the causes for precipitation and fouling with a gray-green deposit of a vessel for the storage of liquid micro fertilizer consisting of ammonium heptamolybdate, potassium chloride, ammonium vanadate, boric acid, chromium trichloride, sodium selenate, and Trilon B as a chelating ligand. The precipitate represented the crystalline 1 : 1 complex of Trilon B with carbamide NaH3L1·(H2N)2CO·H2O (H4L1 = ethylenediaminetetraacetic acid). The deposit on the vessel bottom and wall was formed upon transformation of the molybdenum complex Na4(MoO3)2L1·8H2O into insoluble coordination polymer in an acid medium. Neutralization of the solution to pH 6–7 and a decrease in the concentration of Trilon B gave a violet micro fertilizer solution that was stable during storage. The molecular structure of the NaH3L1·(H2N)2CO·H2O crystal was determined.

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Publication Details

Journal
Russian Journal of Coordination Chemistry
Published
2024-10-01
DOI
https://doi.org/10.1134/s1070328424600608
Primary Topic
Analytical Chemistry and Chromatography
Type
article
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article

Stabilization of an Aqueous Solution of a Liquid Micro Fertilizer Containing Trilon B as a Chelating Agent. Structure of the Molecular Crystal of Sodium Carbamide Ethylenediaminetetraacetate Hydrate NaH3L1·(H2N)2CO·H2O

Н. М. Лазарев, В. В. Семенов, E.V. Baranov, Н. В. Золотарева et al.
Russian Journal of Coordination Chemistry
Analytical Chemistry and Chromatography
article

Stabilization of an Aqueous Solution of a Liquid Micro Fertilizer Containing Trilon B as a Chelating Agent. Structure of the Molecular Crystal of Sodium Carbamide Ethylenediaminetetraacetate Hydrate NaH3L1·(H2N)2CO·H2O

Н. М. Лазарев, В. В. Семенов, E.V. Baranov, Н. В. Золотарева, Б. И. Петров
article en

Abstract

Chemical analysis methods were used to identify the causes for precipitation and fouling with a gray-green deposit of a vessel for the storage of liquid micro fertilizer consisting of ammonium heptamolybdate, potassium chloride, ammonium vanadate, boric acid, chromium trichloride, sodium selenate, and Trilon B as a chelating ligand. The precipitate represented the crystalline 1 : 1 complex of Trilon B with carbamide NaH3L1·(H2N)2CO·H2O (H4L1 = ethylenediaminetetraacetic acid). The deposit on the vessel bottom and wall was formed upon transformation of the molybdenum complex Na4(MoO3)2L1·8H2O into insoluble coordination polymer in an acid medium. Neutralization of the solution to pH 6–7 and a decrease in the concentration of Trilon B gave a violet micro fertilizer solution that was stable during storage. The molecular structure of the NaH3L1·(H2N)2CO·H2O crystal was determined.

Russian Journal of Coordination ChemistryVol. 50(10)
G.A. Razuvaev Institute of Organometallic Chemistry (RU)
Clean water and sanitation
Openalex Percentile: Top 83%
Analytical Chemistry and Chromatography
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