Síntese e Caracterização de Bioadsorvente de Spondias mombin L. para Remoção de Azul de Metileno utilizando ClZn2, NaOH e Al2(SO4)3.14H2O

Objective – The objective of this study was to synthesize and characterize a bioadsorbent produced from Spondias mombin L.’s endocarp, using the chemical activators ClZn2, NaOH and Al2(SO4)3·14H2O, and evaluate its efficiency in removing methylene blue dye from aqueous solutions. Methodology - The research was structured in three stages: preparation and activation of activated charcoal at different temperatures and pyrolysis times; material characterization regarding ash content, moisture content, yield and pH; and carrying out adsorption tests to determine the efficiency of dye removal. Originality/relevance - This study addresses the theoretical gap related to the reuse of agricultural waste to produce adsorbent materials, promoting sustainable alternatives to the use of conventional adsorbents and highlighting their relevance for the treatment of effluents. Results - The adsorbents activated with NaOH and ClZn2 demonstrated greater efficiency, with emphasis on the materials NA250-3, ZN300-2 and ZN300-4, which presented adsorption capacities of 1.40 mg·g⁻¹, 1.39 mg·g⁻ ¹ and 1.37 mg·g⁻¹, removing 93.23%, 93.02% and 91.69% of the dye, respectively. The ZN250-4 material stood out for its balance between performance (1.33 mg·g⁻¹, 88.78% removal) and cost-benefit, due to its high yield (64.27%) compared to the others. Theoretical/methodological contributions: The research expands knowledge about ideal activation conditions and use of chemical activators, providing support for bioadsorbents applications. Social and environmental contributions: The research promotes sustainability by proposing the reuse of agricultural waste as raw materials for the production of biosorbents, reducing environmental pollution and offering solutions for the treatment of effluents.