Facile Synthesis of Perovskite SrSnO <sub>3</sub> /N‐rGO Composite as a Durable Electrocatalyst for Effective Oxygen Reduction Reaction

Abstract Designing a low‐cost, long‐lasting, and active electrocatalyst for the oxygen reduction reaction (ORR) is crucial to replace the high‐cost commercial Pt/C electrocatalyst. We have examined the electrocatalytic activity of a stannate‐based perovskite system modified with N‐doped reduced graphene oxide (SrSnO 3 /NrGO). The sol–gel method was used to synthesize SrSnO 3 nanoparticles. Later on, hydrothermal technique was employed to prepare SrSnO 3 /rGO and SrSnO 3 /NrGO, respectively. We assessed the ORR performance of all the three synthesized catalyst. Compared to SrSnO 3 and SrSnO 3 /rGO, the composites, SrSnO 3 /NrGO exhibit more activity in oxygen reduction processes in a 0.1 M KOH medium with an onset potential of 0.84 V versus RHE. In addition, SrSnO 3 /NrGO exhibits superior stability and better methanol tolerant when compared to commercial Pt/C (20 wt%).

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Publication Details

Journal
ChemistrySelect
Published
2024-12-01
DOI
https://doi.org/10.1002/slct.202404668
Citations
1
Primary Topic
Electrocatalysts for Energy Conversion
Type
article
Field-Weighted Citation Impact
0.10

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article

Facile Synthesis of Perovskite SrSnO 3 /N‐rGO Composite as a Durable Electrocatalyst for Effective Oxygen Reduction Reaction

Bibhuti Bhushan Nayak, Siba Soren, Debendra Behera, Purnendu Parhi
1 citations
ChemistrySelect
Electrocatalysts for Energy Conversion
0.10
article

Facile Synthesis of Perovskite SrSnO 3 /N‐rGO Composite as a Durable Electrocatalyst for Effective Oxygen Reduction Reaction

Bibhuti Bhushan Nayak, Siba Soren, Debendra Behera, Purnendu Parhi
article en
1 citations

Abstract

Abstract Designing a low‐cost, long‐lasting, and active electrocatalyst for the oxygen reduction reaction (ORR) is crucial to replace the high‐cost commercial Pt/C electrocatalyst. We have examined the electrocatalytic activity of a stannate‐based perovskite system modified with N‐doped reduced graphene oxide (SrSnO 3 /NrGO). The sol–gel method was used to synthesize SrSnO 3 nanoparticles. Later on, hydrothermal technique was employed to prepare SrSnO 3 /rGO and SrSnO 3 /NrGO, respectively. We assessed the ORR performance of all the three synthesized catalyst. Compared to SrSnO 3 and SrSnO 3 /rGO, the composites, SrSnO 3 /NrGO exhibit more activity in oxygen reduction processes in a 0.1 M KOH medium with an onset potential of 0.84 V versus RHE. In addition, SrSnO 3 /NrGO exhibits superior stability and better methanol tolerant when compared to commercial Pt/C (20 wt%).

ChemistrySelectVol. 9(46)
Rama Devi Women's University (IN), Ravenshaw University (IN)
Council of Scientific and Industrial Research, India
Openalex Percentile: Top 63%
Electrocatalysts for Energy Conversion
0.10
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