Facile Synthesis of Perovskite SrSnO <sub>3</sub> /N‐rGO Composite as a Durable Electrocatalyst for Effective Oxygen Reduction Reaction
Abstract Designing a low‐cost, long‐lasting, and active electrocatalyst for the oxygen reduction reaction (ORR) is crucial to replace the high‐cost commercial Pt/C electrocatalyst. We have examined the electrocatalytic activity of a stannate‐based perovskite system modified with N‐doped reduced graphene oxide (SrSnO 3 /NrGO). The sol–gel method was used to synthesize SrSnO 3 nanoparticles. Later on, hydrothermal technique was employed to prepare SrSnO 3 /rGO and SrSnO 3 /NrGO, respectively. We assessed the ORR performance of all the three synthesized catalyst. Compared to SrSnO 3 and SrSnO 3 /rGO, the composites, SrSnO 3 /NrGO exhibit more activity in oxygen reduction processes in a 0.1 M KOH medium with an onset potential of 0.84 V versus RHE. In addition, SrSnO 3 /NrGO exhibits superior stability and better methanol tolerant when compared to commercial Pt/C (20 wt%).
Authors
- Bibhuti Bhushan Nayak
- Siba Soren (ORCID: https://orcid.org/0000-0003-0352-8938)
- Debendra Behera
- Purnendu Parhi (ORCID: https://orcid.org/0000-0003-0021-4378)
Institutions
- Rama Devi Women's University (IN)
- Ravenshaw University (IN)
Publication Details
- Journal
- ChemistrySelect
- Published
- 2024-12-01
- DOI
- https://doi.org/10.1002/slct.202404668
- Citations
- 1
- Primary Topic
- Electrocatalysts for Energy Conversion
- Type
- article
- Field-Weighted Citation Impact
- 0.10
Funders
- Council of Scientific and Industrial Research, India