Developing chiral aggregates exhibiting anti-S-shaped CD-ee dependence: using a <i>meso</i>-isomer to tune dynamic aggregates induced by enantiomers

We report the use of the <i>meso</i>-isomer of tartaric acid, <i>meso</i>-tartaric acid, to tune the chirality of the dynamic aggregates of a perylenebisimide dye bearing boronic acid groups in the presence of enantiomeric L-/D-tartaric acid. The CD-ee dependence changes from S- to anti-S-shaped. A change in the structures of the chiral aggregates led by the <i>meso</i>-tartaric acid is identified.

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Publication Details

Journal
Chemical Communications
Published
2024-12-06
DOI
https://doi.org/10.1039/d4cc05345a
Primary Topic
Electrostatics and Colloid Interactions
Type
article
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Developing chiral aggregates exhibiting anti-S-shaped CD-ee dependence: using a meso-isomer to tune dynamic aggregates induced by enantiomers

Xin Wu, Xiaosheng Yan, Xiaoyan Lin, Yun‐Bao Jiang et al.
Chemical Communications
Electrostatics and Colloid Interactions
article

Developing chiral aggregates exhibiting anti-S-shaped CD-ee dependence: using a meso-isomer to tune dynamic aggregates induced by enantiomers

Xin Wu, Xiaosheng Yan, Xiaoyan Lin, Yun‐Bao Jiang, Zhao Li, Jianbin Lin, Xuan‐Xuan Chen, Juanzi Shi, Yue-Bo Yu, Qian Wang
article en

Abstract

We report the use of the <i>meso</i>-isomer of tartaric acid, <i>meso</i>-tartaric acid, to tune the chirality of the dynamic aggregates of a perylenebisimide dye bearing boronic acid groups in the presence of enantiomeric L-/D-tartaric acid. The CD-ee dependence changes from S- to anti-S-shaped. A change in the structures of the chiral aggregates led by the <i>meso</i>-tartaric acid is identified.

Chemical CommunicationsVol. 61(9)
Xiamen University (CN)
Openalex Percentile: Top 74%
Electrostatics and Colloid Interactions
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