Methane Adsorption Energy Variation Affected by Industrial Components in Deep and Thick Coal Reservoirs

The relevant literature indicates that coal facies have a significant impact on the pore structure and adsorption properties of deep coal reservoirs. The content of submicroscopic components is used to calculate the parameters of coal facies. Based on traditional coal phase parameters and ash content, the coal phases of the coal samples in the study area were divided. Based on the adsorption potential theory, the differences in methane adsorption energy changes between different coal phases were compared. The results are as follows. The wet herbaceous swamp facies (type A) could be divided into two subtypes by using the ash yield: subtype A-1 (with an ash yield lower than 20% and a gel index (GI) lower than 5), and subtype A-2 (with an ash yield larger than 20% and a GI lower than 5). With the increase in micro-pore volume shown in A-1 samples, cumulative surface free energy increases linearly and the maximum rate of decline decreases linearly. Coal facies have an important effect on adsorption parameters: VL increases and PL decreases with higher structural preservation index (TPI). The effect of a low ash yield and different Ro,max on methane adsorption energy parameters is stronger.